In the area of Bernauerstraße on Sundays there are markets with quite a few dealers in all kinds of new and old things, including coins. Last year I got a few GDR coins as well as a Nazi 5 Marks. Some will ask for too high prices, so you have to make an offer.
You can combine that with a visit of the remains of the Wall along Bernauerstraße. This is one of the main areas to learn about the Wall.