As previously said, an API is intended for usage by computer programmers, not directly by users.
I'm still puzzled by your needs for communicating with Numista inside Excel. Are you interested in keeping an Excel spreadsheet synchronized with Numista servers, so that changing the spreadsheets sends an update to Numista, and updating your collection on Numista updates your spreadsheet?
If so, I guess that a competent computer programmer, with a good amount of time and trial-and-error, could do that with a RealTimeData server API or something like this (I'm not so sure because I've never programmed custom Excel features). Doing that would require a lot of hard work (and should be constantly maintained, so that changes in Numista's spreadsheets exports don't break nothing), either by the Numista team or volunteers.